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Phenolic resin is a synthetic polymer material, which is made by polycondensation of phenols and aldehydes. The phenolic resin for refractories has excellent heat resistance, mechanical strength, and chemical resistance. Their thermal decomposition temperature is usually between 300 and 600 ° C, which makes them maintain stable performance under high temperature conditions. Phenolic resin also has good wear resistance and oxidation resistance, so it performs well in extreme environments. The low thermal conductivity of this resin contributes to the thermal insulation effect of the refractory.
Phenolic resin is widely used in the field of refractory materials, mainly used as a binder and impregnating agent for refractory bricks, refractory castables and other refractory products. As an adhesive, it can enhance the mechanical strength and heat resistance of the refractory material, and ensure that the material is not easy to fall off and crack at high temperatures. As an impregnant, the phenolic resin can penetrate into the microporous structure of the refractory material to improve its compactness and corrosion resistance. This resin is also widely used in the lining materials of metallurgical, ceramic and chemical equipment to protect and extend the service life of the equipment.
The main raw materials of phenolic resin include phenolic compounds (such as phenol) and aldehyde compounds (such as formaldehyde). Phenol is usually extracted from petrochemicals, while formaldehyde is produced by methanol oxidation. The purity and reaction conditions (such as temperature, pH) of phenol and formaldehyde directly affect the quality and performance of phenolic resin. In addition to phenols and aldehydes, catalysts (such as acidic or basic catalysts) and other additives (such as plasticizers and curing agents) are also essential raw materials in the production process. The stable supply and quality control of upstream raw materials is a key to ensure the performance of phenolic resin products.
Phenolic resin is widely used in refractory materials, and its market demand mainly comes from high-temperature industries such as steel, non-ferrous metals, glass and ceramics. With the advancement of global industrialization and the expansion of infrastructure construction, the demand for high-performance refractories is increasing. Especially in the iron and steel industry, refractory bricks and castables made of phenolic resin are widely used in the lining of key equipment such as blast furnaces, converters, and electric furnaces. In the future, with the improvement of environmental protection requirements and the development of new material technology, the market demand for phenolic resins will continue to grow, and may develop in more high-end and refined directions.
Phenolic resin has higher requirements for storage conditions, mainly including temperature, humidity and environmental control. The resin should be stored in a cool, dry and well-ventilated environment, avoiding direct sunlight and high temperature to prevent premature curing and performance deterioration. It is generally recommended that the storage temperature should not exceed 25 ℃ and the humidity should be controlled below 60%. Phenolic resin has a certain degree of volatility, and long-term exposure to the air may cause the volatilization and loss of some components, so it should be sealed and stored. In order to prevent fire and explosion accidents, the storage area should be far away from fire sources and flammable and explosive materials, and fire prevention facilities should be equipped if necessary.
The production process of phenolic resin mainly includes solution polymerization and melt polymerization. The solution polymerization process has the advantages of low reaction temperature and easy control, but there are problems of solvent recovery and environmental pollution, and the melt polymerization avoids the use of solvents, which is more environmentally friendly, but requires higher control of reaction conditions. In recent years, with the enhancement of environmental awareness and technological progress, the application of green technology and high-efficiency catalysts has gradually increased, which helps to improve production efficiency and product quality. The introduction of intelligent and automation technology is also gradually optimizing the production process and reducing costs.
Phenolic resin in the production and use of the process will produce certain harmful substances, such as formaldehyde and phenol, these substances have potential hazards to the environment and human health. Therefore, environmental protection and safety are important considerations in the production and use of phenolic resins. Enterprises need to strictly abide by the relevant environmental regulations, the use of advanced waste gas, wastewater treatment technology, reduce emissions. In the process of production and use, strengthen personal protection and safety management to ensure the health and safety of operators. In the future, with the increasingly stringent environmental protection regulations and the development of green chemical technology, low-toxic, non-toxic alternatives and new environmental protection processes will gradually become the direction of industry development.
The competition in the phenolic resin industry is fierce, mainly in product quality, price and technical services. In the global market, Europe, America and Asia are the main production and consumption markets, with a number of leading enterprises and technologies. With the change of market demand and the application of new technologies, enterprises need to constantly innovate and improve product performance and added value to maintain competitiveness. In the future, the development trend of phenolic resin industry will focus on high performance, multi function and environmental protection, and globalization and regional cooperation will further promote the integration and optimization of the industry.
Phenolic resin for refractory materials has a broad application prospect in modern industry, and its excellent performance makes it an indispensable important material for high temperature industry. By optimizing the production process, strengthening environmental protection and safety management and continuous technological innovation, the phenolic resin industry will usher in a brighter future.
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